The move comes as Vedanta's parent, Vedanta Resources, tries to trim its debt amid concerns over its ability to meet financial obligations.
It also follows a lapse in Hindustan Zinc Ltd's proposed deal to buy zinc assets from Vedanta for $2.98 billion.
Shrivastava joins Vedanta from the Holcim Group where she
worked as the CFO for Asia Pacific, Middle East & Africa
operations, Vedanta said in a statement.
Last week, Vedanta posted a 68% slump in fourth-quarter
profit amid declining prices of metals.
(Reporting by Chris Thomas and Kashish Tandon in Bengaluru)